Helvetica Chimica Acta p. 580 - 586 (1986)
Update date:2022-08-05
Topics:
Carroy, Annick
Langick, C. Richard
Lehn, Jean-Marie
Matthes, Karen E.
Parker, David
The synthesis of a series of phosphine-functionalised macrocycles, 1-6, is described.The combination of N- and O-sites with P- and S-sites provides ligands which may bind transition or non-transition metal ions; as a consequence, they give access to dinuclear complexes containing both a Lewis acid and a redox metallic site.Compounds 1,2 and 6 are heterodinucleating ligands capable of binding two dissimilar metals in proximity.Macrocycles 3-5 are homotopic ligands which may form homodinuclear complexes of transition metals.
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