Tetrahedron p. 9899 - 9914 (1999)
Update date:2022-08-04
Topics:
De Napoli, Lorenzo
Di Fabio, Giovanni
Messere, Anna
Montesarchio, Daniela
Musumeci, Domenica
Piccialli, Gennaro
Protected forms of 1,2,3-propanetriol and cis, cis-1,3,5- cyclohexanetriol were incorporated onto solid supports which were exploited in the solid phase synthesis of 3'-3' linked oligodeoxyribonucleotides (ODNs), involving only nucleoside 3'-phosphoramidites as building blocks. UV thermal denaturation analysis showed the ability of ODNs with this inversion of polarity motif to cooperatively hybridize with duplexes of the type 5'- (Pu)(m)(Py)(n)-3' in an alternate strand recognition approach.
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