Journal of the Chemical Society. Perkin transactions I p. 2385 - 2389 (1996)
Update date:2022-08-30
Topics:
Suzuki, Hitomi
Yonezawa, Shuji
Nonoyama, Nobuaki
Mori, Tadashi
In the presence of molecular oxygen and a catalytic amount of tris(pentane-2,4-dionato)iron(III), non-activated and moderately activated arenes, which include alkylbenzenes, halogenobenzenes, phenolic ethers, naphthalene and derivatives, can be nitrated with nitrogen dioxide at ice-bath temperature or below to give the corresponding nitro derivatives in fair to good yields. An electron-transfer mechanism has been proposed, where an activated NO2-FeIII complex plays a key role in the cyclic process for converting arenes into nitroarenes.
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