Bulletin of the Chemical Society of Japan p. 2595 - 2602 (1995)
Update date:2022-08-29
Topics:
Firouzabadi, Habib
Afsharifar, Gholam Reza
1-Benzyl-4-aza-1-azoniabicyclo<2.2.2>octane tetrahydroborate (BAAOTB) and tetrabutylammonium tetrahydroborate (TBATB) are used for the selective reductions of aldehydes, ketones, α,β-unsaturated carbonyl compounds, acid chlorides, azides, epoxides, and disulfides in t-BuOH and hexane/chloroform.ABBOAB with its rigid and bulky structure reacts more selectively than its analogue TBATB.
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