Phosphorus, Sulfur and Silicon and the Related Elements p. 125 - 147 (1998)
Update date:2022-08-11
Topics:
Firouzabadi, Habib
Adibi, Mina
Methyltriphenylphosphonium tetrahydroborate as a stable quaternary phosphonium borohydride is introduced. This compound is able to reduce aldehydes, ketones, acyl chlorides, and azides efficiently in CH2Cl2. α,β-Unsaturated carbonyl compounds are reduced selectively via 1,2-reduction. The effect of Lewis acids upon the mode and the rate of the reaction of epoxides and acetophenone are also described. This reagent is also able to bring about reductions effectively in the absence of solvent.
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