Tetrahedron Letters p. 8751 - 8754 (1994)
Update date:2022-08-11
Topics:
Kovac, F.
Baumstark, A. L.
Dimethyldioxirane converts p-substituted α-methylbenzyl alcohols to the corresponding acetophenones in excellent yield with α-hydroxyacetophenones as the minor products; the oxidation shows a ρ of -1.57, PKIE of 3.55, KIE of 1.09 for OD and activation parameters with a large, negative ΔS* term.
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