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Green Chemis
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DOI: 10.1039/C6GC01272H
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COMMUNICATION
(
g) M. Frigerio and M. Santagostino, Tetrahedron Lett,
994, 35, 8019-8022; (h) A. E. J. d. Nooy, A. C. Besemer and
Chem., 1999, 38, 2554-2562; (d) J. P. Fackler, Inorg. Chem.,
2002, 41, 6959-6972; (e) M. H. Baik, M. Newcomb, R. A.
Friesner and S. J. Lippard, Chem. Rev., 2003, 103, 2385-
2420.
1
H. v. Bekkum, Synthesis., 1996, 1153-1176; (i) M. Uyanik
and K. Ishihara, Chem. Commun., 2009, 2086-2099; (j) R.
Ciriminna and M. Pagliaro, Org. Proc. Res. Dev., 2010, 14
45-251.
For selected reviews on using oxygen gas as oxidant see:
a) I. W. C. E. Arends and R. A. Sheldon, in Modern
,
9
(a) H. Chifotides and K. Dunbar, in Multiple Bonds Between
Metal Atoms, eds. F. A. Cotton, C. Murillo and R. Walton,
Springer-Verlag New York, 2005, ch. 12, pp. 465-589; (b)
M. P. Doyle, in Modern Rhodium-Catalyzed Organic
Reactions, ed. P. A. Evans, Wiley-VCH, 2005, ch. 15, pp.
341-355; (c) K. P. Kornecki, J. F. Berry, D. C. Powers and T.
Ritter, in Progress in Inorganic Chemistry Volume 58, ed. K.
D. Karlin, Wiley-VCH, 2014, ch. 4, pp. 225-302.
2
4
(
Oxidation Methods, ed. J. E. Bäckvall, Wiley-VCH
Weinheim, 2004, pp. 83-118; (b) I. E. Markó, P. R. Giles, M.
Tsukazaki, I. ChellÉ-Regnaut, A. Gautier, R. Dumeunier, F.
Philippart, K. Doda, J. L. Mutonkole, S. M. Brown and C. J.
Urch, in Adv. Inorg. Chem., Academic Press, 2004, vol. 56
,
10 For selected reviews on application of binuclear rodium(II)
complexes for catalysis see: (a) A. J. Esswein and D. G.
Nocera, Chem. Rev., 2007, 107, 4022-4047; (b) J. Du Bois,
Org. Proc. Res. Dev., 2011, 15, 758-762; (c) H. M. L. Davies
and Y. Lian, Acc. Chem. Res., 2012, 45, 923-935; (d) J. L.
Roizen, M. E. Harvey and J. Du Bois, Acc. Chem. Res., 2012,
45, 911-922; (e) A. F. Trindade, J. A. S. Coelho, C. A. M.
pp. 211-240; (c) R. A. Sheldon, I. W. C. E. Arends, G.-J. ten
Brink and A. Dijksman, Acc. Chem. Res., 2002, 35, 774-781;
(
d) T. Mallat and A. Baiker, Chem. Rev., 2004, 104, 3037-
3
058; (e) B.-Z. Zhan and A. Thompson, Tetrahedron, 2004,
, 2917-2935; (f) T. Punniyamurthy, S. Velusamy and J.
6
0
Iqbal, Chem. Rev., 2005, 105, 2329-2364; (g) M. J. Schultz
and M. S. Sigman, Tetrahedron, 2006, 62, 8227-8241; (h)
Q. Cao, L. M. Dornan, L. Rogan, N. L. Hughes and M. J.
Muldoon, Chem. Commun., 2014, 50, 4524-4543; (i) S. D.
McCann and S. S. Stahl, Acc. Chem. Res., 2015, 48, 1756-
Afonso, L. F. Veiros and P. M. P. Gois, ACS Catal., 2012, 2,
370-383.
11 F. P. Pruchnik, F. Robert, Y. Jeannin and S. Jeannin, Inorg.
Chem., 1996, 35, 4261-4263.
1
766.
For selected reviews on dehydrogenation reactions see: (a)
G. E. Dobereiner and R. H. Crabtree, Chem. Rev., 2010, 110
81-703; (b) J. Choi, A. H. R. MacArthur, M. Brookhart and
A. S. Goldman, Chem. Rev., 2011, 111, 1761-1779; (c) A. C.
Marr, Catal. Sci. Technol., 2012, , 279-287; (d) C.
Gunanathan and D. Milstein, Science, 2013, 341, 1229712;
e) M. Trincado, D. Banerjee and H. Grutzmacher, Energ.
Environ. Sci., 2014, , 2464-2503.
12 For selected reviews on aqueous reactions see: (a) C. J. Li,
Chem. Rev., 1993, 93, 2023-2035; (b) U. M. Lindström,
Chem. Rev., 2002, 102, 2751-2772; (c) C. J. Li, Chem. Rev.,
2005, 105, 3095-3166; (d) A. Chanda and V. V. Fokin,
Chem. Rev., 2009, 109, 725-748; (e) M. O. Simon and C. J.
Li, Chem. Soc. Rev., 2012, 41, 1415-1427.
5
6
7
,
6
2
13 G. J. ten Brink, I. W. C. E. Arends and R. A. Sheldon, Science,
2000, 287, 1636-1639.
(
7
14 B. P. Buffin, J. P. Clarkson, N. L. Belitz and A. Kundu, J. Mol.
Catal. A: Chem., 2005, 225, 111-116.
Examples of binuclear catalysts for alcohol oxidation: (a) S.
Shinoda, H. Moriyama, Y. Kise, Y. Saito, J. Chem. Soc.,
Chem. Commun. 1978, 348-349; (b) D. M. Roundhill, J. Am.
Chem. Soc., 1985, 107, 4354-4356; (c) E. L. Harvey, A. E.
Stiegman, A. Vlcek, H. B. Gray, J. Am. Chem. Soc., 1987,
15 T. Zweifel, J. V. Naubron and H. Grützmacher, Angew.
Chem. Int. Ed., 2009, 48, 559-563.
16 L. Liu, M. Yu, B. B. Wayland and X. Fu, Chem. Commun.,
2010, 46, 6353-6355.
1
09, 5233-5235; (d) N. Komiya, T. Nakae, H. Sato, T. Naota,
17 R. Kawahara, K. I. Fujita and R. Yamaguchi, J. Am. Chem.
Soc., 2012, 134, 3643-3646.
Chem. Commun., 2006, 4829-4831; (e) M. O. Ratnikov, M.
P. Doyle, Mendeleev Commun., 2014, 24, 187-196.
18 Y. Maenaka, T. Suenobu and S. Fukuzumi, J. Am. Chem.
Soc., 2012, 134, 9417-9427.
For selected reviews on enzymes with binuclear metal
centres as active sites see: (a) R. E. Stenkamp, Chem. Rev.,
19 E. Balaraman, E. Khaskin, G. Leitus and D. Milstein, Nat.
1
994, 94, 715-726; (b) K. A. Magnus, H. Ton-That and J. E.
Chem., 2013, 5, 122-125.
Carpenter, Chem. Rev., 1994, 94, 727-735; (c) A. L. Feig and
S. J. Lippard, Chem. Rev., 1994, 94, 759-805; (d) J. B.
Howard and D. C. Rees, Chem. Rev., 1996, 96, 2965-2982;
20 (a) J. H. Choi, L. E. Heim, M. Ahrens and M. H. G. Prechtl,
Dalton Trans., 2014, 43, 17248-17254; (b) P. Sponholz, D.
Mellmann, C. Cordes, P. G. Alsabeh, B. Li, Y. Li, M. Nielsen,
(
(
e) L. Que and Y. Dong, Acc. Chem. Res., 1996, 29, 190-196;
f) B. J. Wallar and J. D. Lipscomb, Chem. Rev., 1996, 96
625-2658; (g) J. Du Bois, T. J. Mizoguchi and S. J. Lippard,
H. Junge, P. Dixneuf and M. Beller, ChemSusChem, 2014, 7,
,
2419-2422; (c) J. Malineni, H. Keul, and M. Moller, Dalton
Trans., 2015, 44, 17409-17414; (d) Y. Sawama, K. Morita, T.
Yamada, S. Nagata, Y. Yabe, Y. Monguchi and H. Sajiki,
Green Chem., 2014, 16, 3439-3443.
2
Coord. Chem. Rev., 2000, 200–202, 443-485; (h) T. D. H.
Bugg, Tetrahedron, 2003, 59, 7075-7101; (i) J. Weston,
Chem. Rev., 2005, 105, 2151-2174; (j) P. Haack and C.
Limberg, Angew. Chem. Int. Ed., 2014, 53, 4282-4293.
For selected reviews on the application binuclear metal
complexes for catalysis see: (a) J. Halpern, Inorg. Chim.
Acta., 1982, 62, 31-37; (b) D. G. McCollum and B. Bosnich,
Inorg. Chim. Acta., 1998, 270, 13-19; (c) B. Bosnich, Inorg.
21 (a) J. H. Barnard, C. Wang, N. G. Berry, J. L. Xiao, Chem. Sci.,
2013, 4, 1234-1244; (b) J. J. Wu, D. Talwar, S. Johnston, M.
8
Yan, J. L. Xiao, Angew. Chem. Int. Ed., 2013, 52, 6983-6987;
(c) D. Talwar, A. Gonzalez-de-Castro, H. Y. Li, J. L. Xiao,
Angew. Chem. Int. Ed., 2015, 54, 5223-5227; (d) J. J. Cheng,
M. J. Zhu, C. Wang, J. J. Li, X. Jiang, Y. W. Wei, W. J. Tang, D.
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