3167
K. A. Aravinda Kumar et al.
Paper
Synthesis
HRMS (ESI, +): m/z [M+] calcd for C12H20O2: 196.1458; found: [M + H+]
197.1530
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Crotonic Acid (3z)15k
White color solid; yield: 0.059 g (58%); mp 181 °C.
1H NMR (500 MHz, CDCl3): δ = 12.34 (s, 1 H), 7.17–7.01 (m, 1 H),
5.91–5.79 (m, 1 H), 1.98–1.76 (m, 3 H).
13C NMR (126 MHz, CDCl3): δ = 172.3, 147.6, 122.2, 18.0.
MS (ESI, +): m/z = 87.2 [M+ + 1].
Acknowledgment
V.V. thanks UGC for the award of fellowship. The funding support
from CSIR funded project BSC0108 is gratefully acknowledged. IIIM
communication No.: IIIM/1779/2015
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Supporting Information
Supporting information for this article is available online at
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© Georg Thieme Verlag Stuttgart · New York — Synthesis 2015, 47, 3161–3168