Tetrahedron p. 8203 - 8208 (1994)
Update date:2022-08-16
Topics:
Vona, Maria Luisa Di
Luchetti, Luciana
Rosnati, Vittorio
The Zn/AcOH reduction of 1 leads only to the carbonyl reduction, while C-decyanation occurs in the case of 2.The mechanism of the latter reaction is discussed.The N-decyanation of N-cyanoamines 3 and 4 involves an ionic mechanism, leading to N-acyl derivatives and isocyanic acid, the latter compound being ultimately reduced to formic acid.
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