RSC Advances
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¨
G. Sourkouni-Argirusi, G. Jas, H. Schonfeld, U. Kunz and
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´
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H. Sajiki, Tetrahedron, 2014, 70, 4790–4798; (c) M. C. Bryan, 11 (a) E. J. Garcıa-Suarez, A. M. Balu, M. Tristany, A. B. Garcıa,
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(c) Y. Zhu, C. N. Lee, R. A. Kemp, N. S. Hosmane and
(ThalesNano Nanotechnology Inc.) was used as a base
equipment. In the X-Cube™ reactor, hydrogen gas is
provided from an external gas cylinder. The cartridge of
ARP-Pt can be used in H-Cube™ ow reactor which is the
similar ow system equipped with a hydrogen generator.
J. A. Maguire, Chem.–Asian J., 2008, 3, 650–662; (d) K. An 13 The Pt loading of ARP was determined by ICP analysis (0.242
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mmol gꢂ1).
7 Typical recent reports for hydrogenation using Pd 14 The reaction space volume in the catalyst cartridge was
nanoparticles; (a) R. Linhardt, Q. M. Kainz, R. N. Grass,
W. J. Stark and O. Reiser, RSC Adv., 2014, 4, 8541–8549; (b)
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I. A. Ibrahim, J. Catal., 2012, 286, 184–192; (e) Y. Wang,
A. V. Biradar, C. T. Duncan and T. Asefa, J. Mater. Chem.,
2010, 20, 7834–7841; (f) J. Li, X.-Y. Shi, Y.-Y. Bi, J.-F. Wei
determined as follows. A preweighed catalyst cartridge was
packed with ARP-Pt (300 mg, 0.085 mmol Pt) and sealed
on either end with 8 mm lters. Aer wetting the cartridge
with EtOH, the wet catalyst cartridge was weighed. The
reaction volume was determined from the weight
difference between the dry and the wet cartridges to be
0.36 mL. Then, the contact time was calculated from the
following equation: contact time [s] ¼ 0.36 [mL; reaction
space volume in the catalyst cartridge] ꢁ 60/ow rate
[mL minꢂ1].
¨
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45766 | RSC Adv., 2015, 5, 45760–45766
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