10.1002/adsc.201800786
Advanced Synthesis & Catalysis
and then cooled down to room temperature. Organic
[8] V. Polshettiwar, B. Baruwati, R. S. Varma, Green
Chem. 2009, 11, 127-131.
products
were
extracted
from
glycerol
with
dichloromethane (5 x 3 mL) and the solvent was
evaporated under vacuum. All the products were identified
by GC-MS analysis, 1H and 13C NMR spectroscopy,
comparing with the reported data.
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General procedure for recycling of the catalytic phase.
After extraction of the organic products, the catalytic phase
was treated under vacuum at 50 ºC for 2 h and the
appropriated reagents were then added under argon to the
catalytic phase. The reaction mixture was pressurized with
H2 at the appropriated pressure, heated up to the desired
temperature, stirred for the established time, and then
cooled down to room temperature. Organic products were
extracted from glycerol with dichloromethane (5 x 3 mL)
and dried under reduced pressure. This process was
repeated for each of the different runs.
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The Centre National de la Recherche Scientifique (CNRS)
and Université de Toulouse 3 - Paul Sabatier are
gratefully acknowledged for financial support. A. R. thanks
the CONACYT Mexican agency for the PhD scholarship.
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