Journal of Organometallic Chemistry p. 117 - 122 (1989)
Update date:2022-08-16
Topics:
Kvintovics, P.
Heil, B.
Rhpy3Cl3 (py = pyridine) has been found to be a versatile catalyst in selective transfer hydrogenation of α,β-unsaturated ketones to saturated ketones, dienes to monoenes, acetylenes to olefins, and Schiff bases to amines.With catalytic systems formed "in situ" from RhCl3*xH2O and chiral monodentate amines such as R,S(-)-ephedrine, enantioselective reduction of ketones takes place but the optical yields are rather low.
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