Tetrahedron Letters p. 2365 - 2368 (1986)
Update date:2022-08-10
Topics:
Guibe, F.
Dangles, O.
Balavoine, G.
Allyl(All) and Allyloxycarbonyl(Alloc) amino-acid derivatives are deprotected through palladium-catalyzed hydrostannolysis by Bu3SnH in a highly selective manner.Benzyl and benzyloxycarbonyl groups are stable under these conditions.Moreover the allyl and Alloc groups seem orthogonal to the t-butyl and t-butoxycarbonyl protecting groups.
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