Bulletin of the Chemical Society of Japan p. 1759 - 1761 (1994)
Update date:2022-08-16
Topics:
Omote, Kazushi
Aso, Yoshio
Otsubo, Tetsuo
Ogura, Fumio
Tellurium tetraethoxide reacts with primary thioamides at room temperature, forming nitriles in high yields. On the other hand, the reactions with amides are largely temperature-dependent, giving predominantly esters at 80 deg C and nitriles at a higher temperature. Similarly, tellurium tetraethoxide readily induces the C-N bond cleavage of ureas to give carbamates and amines.
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