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17) We have done a similar competitive experiment in CH CN, and
3
the products consisted of 1% cyclohexanol, 2% cyclohexanone, and 39%
cycloheptanone; in this case the relative rate of alcohol is much faster
than in CF CH OH. Apparently oxidation of alcohol is efficient in both
3
2
8
CH CN and CF CH OH, but the oxidation of cyclohexane is much
3
3
2
slower in CH CN. Alcohol may be oxidized by a different mechanism in
3
8
CH CN, such as direct oxidation by coordinated H O .
3
2
2
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