LETTER
Oxidative Cleavage of C=C Bonds
1381
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1O2
base
H
Ac
O
O
O
O
O
AcO–
+
Hbase+
+
R2
R2
O–
O+
H
O
R1
O
R2
H
R1
O
R1
R1
H
1O2
O
+
R2
H
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Scheme 3 A possible pathway for the oxidative cleavage of the C=C
bond of olefins
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Acknowledgment
The authors wish to thank the Research Council of Bu-Ali Sina
University for financial support.
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(48) Caution: Although we did not encounter any problem with
trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane, it is
potentially explosive and should be handled with
© Georg Thieme Verlag Stuttgart · New York
Synlett 2013, 24, 1377–1382