Chemische Berichte p. 1099 - 1103 (1997)
Update date:2022-08-11
Topics:
Volz, Heinrich
Mueller, Wilhelm
The isolation at -78°C and characterization of the novel crystalline reactive porphinatomanganese(IV) complex Mn(TDCPP)(OCl)2 (5) is described. 5 is compared with the porphinatomanganese(IV) complexes Mn(TDCPP){C6H5IOCl)2 (2), Mn(TDCPP)(C6F5IOCl)Cl (3) and Mn(TDCPP)(OCH3)2 (4). The stoichiometric reaction of 5 with triphenylphoshane yields 2.5 equivalents of triphenylphosphane oxide and 1.0 equivalent of Mn(TDCPP)Cl (1). Complex 5 epoxidizes stilbene, and oxygenates and chlorinates cyclohexane. VCH Verlagsgesellschaft mbH.
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