10.1002/cctc.201900242
ChemCatChem
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C-3/C-5 promoted oxidative transformation of styrene in dry MeOH in presence of molecular sieves must give almost negligible
transformation of benzaldehyde. However, we could not able to protect the reaction from moisture under standard Schlenk line during the
collection of reaction mixture at different time interval.
22
Although the addition of NaIO4 produced a color change from orange to green, but we failed to characterize the species.
23
For initial rate kinetics, the conversion data considered for the plot was strictly maintained within the half-life of the reaction.
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Although, the experimental evidences suggest the presence of (L)RuIV=O. However, the presence of other active species such as;
(L)RuIII=O or (L)RuV=O or (L)RuVI(O2) cannot be ruled out from the reaction mixture. For such types of active species please see ref; 12 and
references therein.
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However, the involvement of other active species such as (L)RuVI(O2) in the reaction cannot be ruled out from these analysis. A detailed
investigation would be further required to consider or nullify other possibilities.
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