Advanced Synthesis & Catalysis
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ethanol/methanol as renewable H source and highly
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Experimental Section
t
Nitrobenzene (1a) (100 mg, 0.8130 mmol), NaO Bu
(
156 mg, 1.626 mmol), Rh@PS catalyst (353 mg, 2
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works as reducing source and 1,4-dixonae used as co-
solvent. The reaction mixture was then heated at 100
o
8
026; d) D. Ando, C. Bevan, J. M. Brown, D. W. Price,
C over hot plate magnetic stirrer for 8 hours. After
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completion, the reaction mixture was cooled at room
temperature and then added 1 mL of distilled water.
The organic mixture was extracted with ethyl acetate
and passed though anhydrous sodium sulfate and dried
under reduced pressure. Evaporation of combined
organic layer followed by column chromatography
with (hexane: EtOAc = 9:1) as eluent over silica gel
3
249.
[
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(
(
mesh 60-120) afforded aniline (2a) as brown liquid
68 mg, 90%).
1
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Acknowledgements
We are thankful to the director of CSIR-IHBT for providing
necessary facilities. The authors thank DST Nano Mission Project
[8] a) R. Baruah, M. Dixit, A. Parejiya, P. Basarkar, A.
Bhargav, S. Sharma, Int. J. Hydrogen Energy 2017, 42,
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Wang, W. Cai, Catal. Commun. 2015, 58, 137-140.
(SR/NM/NS-1340/2014) for major financial support and partial
support from CSIR MLP-0203. We also thank Dr. Girish Saini and
AIRF-JNU, New Delhi for the TEM and EDX analysis. S. S. and D.
B. thanks to CSIR, New Delhi for awarding fellowships.
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