Journal of Organometallic Chemistry p. 381 - 390 (1988)
Update date:2022-08-24
Topics:
Vicente, Jose
Chicote, M.Teresa
Bermudez, M.Dolores
Sanchez-Santano, Maria J.
Jones, Peter G.
The reaction ( 1 1) between [Au(2-C6H4CH2NMe2)Cl2] and [HgPh2] gives [Au(2-C6H4CH2NMe2)(Ph)Cl]. From this complex, the neutral [Au(2-C6H4CH2NMe2)(Ph)X] (X : Br, I, CN, MeCO2) complexes are obtained by reaction with X- salts. Cationic complexes [Au(2-C6H4CH2NMe2)(Ph)L]ClO4 (L : pyridine, tetrahydrothiophene) are obtained by treatment of [Au(2-C6H4CH2-NMe2)(Ph)Cl] with ClO4- and the relevant ligand L. The complex [Au(2-C6H4-CH2NMe2)(Ph)Cl] crystallizes in two modifications, both with three independent molecules in the asymmetric unit. The AuN and AuCl bonds are long, consistent with the appreciable trans influence of the C-donor ligands. The molecules differ somewhat in the orientation of the rings.
View MoreTianjin SPHINX SCIENTIFIC LAB.
Contact:+86-022-66211289
Address:Tianda high-tech Park. No.80,the 4th Avenue
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)
Contact:+86-513-83886111
Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.
Contact:+86-512-6585 6968
Address:Changfu Road, Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
TIANJIN NORTH JINHENG CHEMICAL PLANT.
Contact:0086-22-59952083
Address:DongShigu Country In JiXian TianJin China
Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd
website:http://www.jlpharms.com
Contact:+86-571-86982636
Address:Rm A606, Fuyi Center, jianqiao street, Jianggan Area
Doi:10.1021/ol035052i
(2003)Doi:10.3762/bjoc.15.153
(2019)Doi:10.1039/c29690001192
(1969)Doi:10.1021/acs.jmedchem.9b02039
(2020)Doi:10.1016/j.apcata.2020.117622
(2020)Doi:10.1039/C39770000664
(1977)