RSC Advances p. 58151 - 58155 (2014)
Update date:2022-08-11
Topics:
Malcho, Phillip
Garca-Surez, Eduardo J.
Riisager, Anders
Ionic liquids (ILs) have been applied as recyclable reaction media in the decarbonylation of aldehydes in the presence of a rhodium-phosphine complex catalyst. The performance of several new catalytic systems based on imidazolium-based ILs and [Rh(dppp)2]Cl (dppp: 1,3-diphenylphosphinopropane) were excellent in the decarbonylation of both aromatic and aliphatic aldehydes providing >99 yield of benzenes and alkanes, respectively. The catalytic performance depended, however, strongly on the employed IL and its thermal stability. In addition, the ILs afforded good catalyst immobilization as well as a biphasic system with the product allowing recovery and reuse of the employed catalyst.
View MoreChangzhou LanXu Chemical Co.,ltd.
Contact:86-0519-86330911,13656129734,15261186386
Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Shenzhen Tianyuan Pharmaceutical Technology Co., Ltd
website:http://www.tianpharm.com
Contact:86-755-23284190
Address:B302,2 unit, Jin Lian Building, No. 134 Qianjin 2 Road, Taoyuan village, Xixiang Street, Baoan,Shenzhen,China
Hebei Think-Do Environment Co., Ltd
website:http://www.thinkdo-environment.com
Contact:0311-86510809
Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
Suzhou Sibian Chemical Technology Co., Ltd
website:http://www.sibianpharm.com
Contact:+8618169181984,+8618013186906
Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Beijing Cooperate Pharmaceutical Co.,Ltd
Contact:86-01060279497
Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Doi:10.1021/jo981315o
(1998)Doi:10.1002/anie.200803207
(2008)Doi:10.1007/s11164-013-1425-4
(2015)Doi:10.1016/j.ejmech.2006.03.006
(2006)Doi:10.3390/molecules21010112
(2016)Doi:10.1016/j.apcata.2016.03.031
(2016)