Organometallics
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refined by full-matrix least-squares procedures on F with SHELXTL
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version 6.14). All non-hydrogen atoms were refined anisotropically.
Hydrogen atoms on carbon were included in calculated positions and
were refined using a riding model. The hydrogen atoms on boron,
H(1), H(2), and H(3), were located in the Fourier difference map and
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ASSOCIATED CONTENT
Supporting Information
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hn, G.; Robinson, T. P. Chem. Commun.
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Representative NMR spectra of catalytic reactions (PDF)
A CIF file with X-ray crystal structure data for compound
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Sproules, S.; Collison, D.; Whittell, G. R.; Lloyd-Jones, G. C.;
Manners, I. Angew. Chem., Int. Ed. 2013, 52, 437−440.
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23) Pun, D.; Lobkovsky, E.; Chirik, P. J. Chem. Commun. 2007,
AUTHOR INFORMATION
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297−3299.
24) Beweries, T.; Hansen, S.; Kessler, M.; Klahn, M.; Rosenthal, U.
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Dalton Trans. 2011, 40, 7689−7692.
(25) Chapman, A. M.; Haddow, M. F.; Wass, D. F. J. Am. Chem. Soc.
Present Address
Department of Chemistry, University of California, Davis,
California 95616, United States.
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011, 133, 8826−8829.
26) Chapman, A. M.; Wass, D. F. Dalton Transactions 2012, 41,
067−9072.
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Beweries, T. Dalton Transactions 2015, 44, 12103−12111.
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Chem. Sci. 2015, 6, 618−624.
29) Forster, T. D.; Tuononen, H. M.; Parvez, M.; Roesler, R. J. Am.
Notes
The authors declare no competing financial interest.
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ACKNOWLEDGMENTS
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This work was supported by the U.S. National Science
Foundation (CHE-1265608). Initial reactions of (N N)Zr
compounds with amine boranes were conducted by Annalese
Maddox.
Chem. Soc. 2009, 131, 6689−6691.
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DEDICATION
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Gregory L. Hillhouse (1955−2014) was many things to many
people. We dedicate this paper to his caring mentorship and his
love of “hot, new results”.
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