Tetrahedron p. 13231 - 13238 (1994)
Update date:2022-08-16
Topics:
Garcia Martinez
Osio Barcina
Ruiz Diez
Subramanian
gem-Dialkylation or alkylative reduction of α-unbranched aliphatic aldehydes 1 is advantageously achieved by reaction of the corresponding gem-bistriflates 2 with di-n-alkylcyanocuprates or di-sec- and di-tert-alkylcyanocuprates respectively. The reaction of α-branched gem-bistriflates 2 with dialkylcyanocuprates in the presence of boron trifluoride affords the olefins 6 in good yield.
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