Journal of Molecular Catalysis A: Chemical p. 46 - 52 (2015)
Update date:2022-08-29
Topics:
Verma, Sanny
Kumar, Subodh
Shawat, Efrat
Nessim, Gilbert Daniel
Jain, Suman L.
Pyridine functionalized carbon nanofibers (Py-CNFs) were synthesized, characterized and used for the grafting of oxo-rhenium complex i.e., methyltrioxorhenium (MTO) via acid-base ionic interaction. The grafting of MTO to Py-CNFs was confirmed by FTIR, UV-vis, SEM, TEM and TGA analyses. The determination of rhenium content by ICP-AES further suggested the successful immobilization of MTO to the support. The developed heterogeneous material i.e., MTO@Py-CNFs was found to be an efficient catalyst for the oxidation of various secondary as well as tertiary amines to corresponding nitrones or N-oxides, respectively by using hydrogen peroxide. The developed catalyst was readily recovered by centrifugation and reused for subsequent ten runs without any significant loss in catalytic activity.
View MoreContact:+86-531-58668191 58668193 58668196 58661173
Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Springchem New Material Technology Co.,Limited
website:http://www.spring-chem.com
Contact:86-21-62885108
Address:602B, Building 1, No. 641, Tianshan Road
Jiangsu Cale New Material Co.ltd
Contact:+86-515-88334667/88203550
Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Suzhou Health Chemicals Co., Ltd.
website:http://www.healthchems.com
Contact:13776257979
Address:No. 338, Jingang Avenue,
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Doi:10.1021/co400128a
(2014)Doi:10.1039/c39940002679
(1994)Doi:10.1002/mabi.201600532
(2017)Doi:10.1016/j.jorganchem.2020.121483
(2020)Doi:10.1002/cctc.202000148
(2020)Doi:10.1080/10286020.2014.902373
(2014)