Tetrahedron p. 6097 - 6108 (1999)
Update date:2022-08-11
Topics:
Kurono, Nobuhito
Sugita, Kazuya
Takasugi, Shingo
Tokuda, Masao
Organozinc compounds of functionalized alkyl iodide carrying an alkoxycarbonyl, cyano or alkenyl group were prepared in high yields under mild conditions (0°C-r.t., 10min in DMF) by the reaction of iodides with an electrogenerated reactive zinc (EGZn). Cross-coupling of the organozinc compounds with various aryl halides in the presence of 5 mol% Pd(P(o- Tol)3)2Cl2 in THF gave the corresponding cross-coupled products in moderate to high yields. These cross-coupling reactions can be also achieved in one step and in one pot by the use of an electrochemical method utilizing a Pt cathode and Zn anode.
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Doi:10.1063/1.126631
(2000)Doi:10.1021/jf60168a001
(1970)Doi:10.1021/ja00880a034
(1962)Doi:10.1016/S0040-4020(01)93413-1
(1973)Doi:10.1021/ja0535561
(2005)Doi:10.1021/ja01346a027
(1932)