Journal of Organometallic Chemistry p. 193 - 195 (1993)
Update date:2022-08-11
Topics:
Todres, Z. V.
Ionina, E. A.
η6-Chromiumtricarbonyl complexes of stilbene and 4,4'-dimethoxystilbene (both in the cis form as ligands) were prepared.The complexes are stable as dry solids, but disintegrate during exposure at 25 deg C in argon, with liberation of the ligands.They are returned as a mixture of cis-trans isomers.The conversion of cis-trans types observed depends not on the spontaneous isomerization of a ligand in a complex, but on the interaction between the slipping ligand and chromium sesquioxide - the product of the transformation of the Cr(CO)3 fragment.
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