ChemCatChem p. 1893 - 1897 (2019)
Update date:2022-08-17
Topics:
Blackaby, William J. M.
Neale, Samuel E.
Isaac, Connie J.
Sabater, Sara
Macgregor, Stuart A.
Whittlesey, Michael K.
Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism involves the NHC acting as a Br?ns
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