Journal of Organic Chemistry p. 7193 - 7198 (2014)
Update date:2022-08-28
Topics:
Liu, Leifang
Dong, Yan
Pang, Bo
Ma, Jiahai
The Suzuki-Miyaura coupling reactions of potassium aryltrifluoroborates with aryl bromides in water are promoted by the addition of [bmim]PF6 using Pd(OAc)2 as a catalyst and Na2CO3 as a base under air. The quantity of [bmim]PF6 used is crucial to the efficiency of the catalytic system. A wide range of biaryls and polyaryls can be easily prepared in good to excellent yields.
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