Journal of Organometallic Chemistry p. 397 - 404 (1988)
Update date:2022-08-28
Topics:
Kondo, Teruyuki
Tsuji, Yasushi
Watanabe, Yoshihisa
Tetrakis(triphenylphosphine)platinum(0) (Pt(PPh3)4) is an effective catalyst precursor for the carbonylative cross-coupling of alkyl iodides with sodium tetraphenylborate (NaBPh4) which yields the corresponding alkyl phenyl ketones.In the reaction of n-hexyl iodide with NaBPh4, n-hexyl phenyl ketone was obtained in 60percent yield.
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