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We have successfully prepared Pd nanosize particles dispersed on
two types of solid supports, namely 3-aminopropyl functionalized
silica gel and cross-linked poly(4-vinylpyridine-co-styrene) gel.
Thesecatalystsexhibitcatalyticactivityforhydrogenationreaction
using aqueous media and, above all, these catalysts are recyclable.
We are currently considering other applications of these catalysts
on other organic transformations, which we are will report in due
course.
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This work was supported by Ansan Environmental Technology
Development Center (grant 09-2-80-81) and the National Research
Foundation of Korea (grant 2009-000-0000-1611). Y.-W. Chang
acknowledges financial support from the SRC/ERC program of
MEST (grant R11-2005-056-04004-0). Likewise, M.L. and K.A.D.C.
appreciate the financial support from the Korean Ministry of
Education through the second stage of the BK21 project
for the Hanyang University Graduate Program, and M.L. also
acknowledges the Seoul Metropolitan Government for Seoul
Science Fellowship.
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