Journal of the Chemical Society - Faraday Transactions p. 2743 - 2750 (1995)
Update date:2022-08-17
Topics:
Aravindan, Ponnu
Maruthamuthu, Pichai
Dharmalingam, Periasamy
The oxidation kinetics of 4,4'-(dimethylamino)diphenylmethane (DMADPM) by Ce(IV), by the oxoanions, MnO4(1-) and Cr2O7(2-), by peroxides, namely, peroxomonosulfate, peroxodisulfate and H2O2, and by halogens viz., Cl2, Br2 and I2, to the radical cation, DMADPM.(1+) along with further oxidation to the product monocation DMADPM(1+) have been studied by the stopped-flow technique.The first- and second-stage oxidations have been followed by monitoring the formation and decay of DMADPM.(1+) via the absorption at 610 nm.Both formation and decay of DMADPM.(1+) obey total second-order kinetics, first-order each with respect to
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