Synthesis p. 401 - 402 (1990)
Update date:2022-08-29
Topics:
Kotsuki, Hiyoshizo
Yoshimura, Naka
Kadota, Isao
Ushio, Yasuyuki
Ochi, Masamitsu
The reduction of Schiff bases; N-benzylidene- and N-(1-phenylethylidene)arylamines with zinc borohydride in diethyl ether gave the corresponding amines in excellent yield.N-benzylidene-benzyl- and cyclohexylamine, N-(1-phenylethylidene)- and N-(cyclohexylidene)cyclohexylamines, however, require additional treatment with 6 N HCl to liberate the amine-borane complex to give the corresponding amines in quantitative yield.The procedure was also applied in the tandem alkylation-reduction of nitriles to yield 1-phenylalkylamines in good yield.
View Morepuyang hongda shengdao new material co.,ltd.
Contact:+86-393- 4896278
Address:No.29 East Zhongyuan Road
Changzhou Baolong Chemical Industrial Co.,Ltd
website:http://www.czbaolong.com
Contact:0519-85720726 0519-85720721 13951213302
Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
LIAONING DMSO CHEMICALS CO.,LTD.
website:http://www.chinadmso.com
Contact:+86-427-6503033
Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Shijiazhuang Xinsheng Chemical Co., Ltd
Contact:+86-311-85965567
Address:Dongyang industry zone,xinle
Contact:+86-13914766747
Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Doi:10.1021/bi00627a018
(1977)Doi:10.1016/S0040-4020(01)88702-0
(1983)Doi:10.1021/jo00260a005
(1988)Doi:10.1007/s11418-013-0814-8
(2014)Doi:10.1007/s11743-014-1566-5
(2014)Doi:10.1016/0022-5088(83)90397-1
(1983)