Journal of Organic Chemistry p. 8685 - 8687 (2002)
Update date:2022-08-23
Topics:
Kitamura, Masato
Lee, Donghyun
Hayashi, Shinnosuke
Tanaka, Shinji
Yoshimura, Masahiro
A Cp*Rh(III) complex catalyzes reductive amination of ketones using HCOONH4 at 50-70°C to give the corresponding primary amines in high yields. The reaction is clean and operationally simple and proceeds at a lower temperature and with higher chemoselectivity than the original Leuckart-Wallach reaction. The new method has been applied to the synthesis of α-amino acids directly from α-keto acids.
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