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Green Chemistry
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Journal Name
ARTICLE
STEM images were collected with a JEOL ARM200F microscope
equipped with a probe aberration corrector and a coldFEG
operated at 200 kV. EDX elemental mappings were performed
using a JEOL Centurio with a solid angle of 0.98 Sr and a
detection area of 100 mm². For this, the samples were
deposited on standard 300 mesh Cu grids with a holey and thin
carbon film coating from an ethanol dispersion.
Wiley-VCH Verlag GmbH, 2003.
19 J. Zakzeski, P. C. A. Bruijnincx, A. LD. OJIo: n10g.e10ri3u9s/Ca9nGdC0B26. 2M5H.
Weckhuysen, Chem. Rev., 2010, 110, 3552–3599.
20 M. Weber, M. Weber and M. Kleine-Boymann, in Ullmann’s
Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH
& Co. KGaA, 2004, pp. 503–519.
21 Z. Chen, H. Zeng, H. Gong, H. Wang and C. Li, Chem. Sci., 2015,
6, 4174–4178.
22 V. R. Jumde, E. Petricci, C. Petrucci, N. Santillo, M. Taddei and
L. Vaccaro, Org. Lett., 2015, 17, 3990–3993.
23 Z. Qiu, J.-S. Li and C.-J. Li, Chem. Sci., 2017, 8, 6954–6958.
24 Z. Chen, H. Zeng, S. A. Girard, F. Wang, N. Chen and C. J. Li,
Angew. Chem. - Int. Ed., 2015, 54, 14487–14491.
25 P. Tomkins, C. Valgaeren, K. Adriaensen, T. Cuypers and D. E.
De Vos, J. Catal., 2019, 371, 207–213.
26 T. Cuypers, P. Tomkins and D. E. De Vos, Catal. Sci. Technol.,
2018, 8, 2519–2523.
27 P. Tomkins, C. Valgaeren, K. Adriaensen, T. Cuypers and D. E.
De Vos, ChemCatChem., 2018, 10, 3689-3693.
28 Z. Qiu, L. Lv, J. Li, C.-C. Li and C.-J. Li, Chem. Sci., 2019, 10,
4775–4781.
29 K. Shimizu, K. Kon, W. Onodera, H. Yamazaki and J. N. Kondo,
ACS Catal., 2013, 3, 112–117.
30 K. Shimizu, N. Imaiida, K. Kon, S. M. A. Hakim Siddiki and A.
Satsuma, ACS Catal., 2013, 3, 998–1005.
31 K. Shimizu, S. Kanno, K. Kon, S. M. A. Hakim Siddiki, H. Tanaka
and Y. Sakata, Catal. Today, 2014, 232, 134–138.
32 W. Wang, Q. Yu, Q. Zhang, S. Mei, J. Yuan, F. Zhao, J. Yang and
J. Lu, ChemistrySelect, 2017, 2, 8818–8823.
33 J. He, X. H. Lu, Y. Shen, R. Jing, R. F. Nie, D. Zhou and Q. H. Xia,
Mol. Catal., 2017, 440, 87–95.
34 A. Li, K. Shen, J. Chen, Z. Li and Y. Li, Chem. Eng. Sci., 2017, 166,
66–76.
35 A. Yuk, K. Leung, K. Hellgardt, K. Kuok and M. Hii, ACS Sustain.
Chem. Eng., 2018, 6, 5479–5484.
36 N. Hadian, M. Rezaei, Z. Mosayebi and F. Meshkani, J. Nat. Gas
Chem., 2012, 21, 200–206.
37 M. Chalid, H. J. Heeres and A. A. Broekhuis, Procedia Chem.,
2012, 4, 260–267.
38 D. Prat, A. Wells, J. Hayler, H. Sneddon, C. R. McElroy, S. Abou-
Shehada and P. J. Dunn, Green Chem., 2016, 18, 288–296.
39 C. M. Alder, J. D. Hayler, R. Henderson, A. Redman, L. Shukla,
L. E. Shuster and H. F. Sneddon, Green Chem., 2016, 4, 1166–
1169.
40 G. Busca, Phys. Chem. Chem. Phys., 1999, 1, 723–736.
41 N. C. Jeong, J. S. Lee, E. L. Tae, Y. J. Lee and K. B. Yoon, Angew.
Chem. Int. Ed., 2008, 47, 10128–10132.
42 F. De Schouwer, T. Cuypers, L. Claes and D. E. De Vos, Green
Chem., 2017, 19, 1866–1876.
43 M. Tamura, K. Shimizu and A. Satsuma, Appl. Catal. A Gen.,
2012, 433–434, 135–145.
Conflicts of interest
There are no conflicts to declare.
Acknowledgements
T. C. and C. V. G. thank the Fonds Wetenschappelijk Onderzoek
(FWO-Vlaanderen) for the (post-)doctoral fellowships. D.E.D.V.
acknowledges the FWO for research project funding, the
Flemish government for long-term structural funding through
the Methusalem program, and EoS (FWO-FNRS) for financial
support. I. V. recognizes the Hercules project (AKUL/13/19) for
financial aid. Finally, the authors thank Ka Yan Cheung for the
help with SEM-EDX measurements.
Notes and references
1
P. Roose, K. Eller, E. Henkes, R. Rossbacher and H. Höke, in
Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH
Verlag GmbH & Co. KGaA, 2015, pp. 1–50.
H. Engels, H. Pirkl, R. Albers, R. W. Albach, J. Krause, A.
Hoffmann, H. Casselmann and J. Dormish, Angew. Chem. Int.
Ed., 2013, 9422–9441.
2
3
4
5
6
7
8
9
S. A. Lawrence, Amines: Synthesis, Properties and
Applications, Cambridge University Press, Cambridge, 2005.
J. Royer, Chiral Amine Synthesis. Methods, Developments and
Applications, Wiley-VCH, 2010.
H. U. Blaser, H. Steiner and M. Studer, ChemCatChem, 2009,
1, 210–221.
S. Geun, V. Mishra, J. Ku, B. Kim, H. Sik, Y. Suh, H. Lee, H. Seok
and Y. Jin, Catal. Commun., 2014, 43, 79–83.
P. Tomkins, E. Gebauer-Henke, W. Leitner and T. E. Müller,
ACS Catal., 2015, 5, 203–209.
L. Wang, J. Zhang, H. Wang, Y. Shao, X. Liu, Y. Wang, J. P. Lewis
and F. Xiao, ACS Catal., 2016, 6, 4110–4116.
J. Zhang, L. Wang, Y. Shao, Y. Wang, B. C. Gates and F. Xiao,
Angew. Chem. Int. Ed., 2017, 56, 9747–9751.
10 H. Greenfield, J. Org. Chem., 1964, 29, 3082–3084.
11 S. X. Huang, D. A. Fischer and J. L. Gland, J. Phys. Chem. A,
1996, 3654, 10223–10234.
12 E. Gebauer-Henke, P. Tomkins, W. Leitner and T. E. Müller,
ChemCatChem, 2014, 6, 2910–2917.
13 A. S. Guram, R. A. Rennels and S. L. Buchwald, Angew. Chem.
Int. Ed., 1995, 34, 1348–1350.
44 R. Sokoll, H. Hobert and I. Schmuck, J. Catal., 1990, 284, 276–
284.
45 H. K. Hall and R. B. Bates, Tetrahedron Lett., 2012, 53, 1830–
1832.
46 Y. Yoon, R. Rousseau, R. S. Weber, D. Mei and J. A. Lercher,
ACS Catal., 2014, 136, 10287–10298
14 J. X. Qiao and P. Y. S. Lam, in Boronic Acids: Preparation and
Applications in Organic Synthesis, Medicine and Materials,
Wiley-VCH Verlag GmbH & Co. KGaA., 2011, pp. 315–361.
15 S. Bähn, S. Imm, L. Neubert, M. Zhang, H. Neumann and M.
Beller, ChemCatChem, 2011, 3, 1853–1864.
16 B. Galabov, D. Nalbantova, P. V. R. Schleyer and H. F. Schaefer,
Acc. Chem. Res., 2016, 49, 1191–1199.
47 X. Kong, Y. Gong, S. Mao and Y. Wang, ChemNanoMat, 2018,
4, 432–450
48 D. Cao, H. Zeng and C.-J. Li, ACS Catal., 2018, 8, 8873–8878.
49 N. Yoshimura, I. Moritani, T. Shimamura and S. Murahashi, J.
Am. Chem. Soc., 1973, 95, 3038–3039.
50 S.-I. Murahashi, N. Yoshimura, T. Sumiyama and T. Kojima, J.
Am. Chem. Soc., 1983, 5002–5011.
51 S. P. Bawane and S. B. Sawant, Chem. Eng. J., 2004, 103, 13–
19.
17 R. Dorel, C. P. Grugel and A. M. Haydl, Angew. Chem. Int. Ed.,
2019, 58, 2–14.
This journal is © The Royal Society of Chemistry 20xx
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