Tetrahedron p. 3229 - 3234 (1984)
Update date:2022-08-17
Topics:
Toussaint, Olivier
Capdevielle, Patrice
Maumy, Michel
Copper(I) salts of arylacetic acids 1 RCO2H readily undergo a catalytic and quantitative decarboxylation in acetonitrile leading to hydrocarbons 2 RH when the corresponding carbanions R(1-) are stabilized by resonance and/or electronwithdrawing substituents.
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