Dalton Transactions p. 14591 - 14602 (2016)
Update date:2022-08-17
Topics:
Pretorius, René
Fructos, Manuel R.
Müller-Bunz, Helge
Gossage, Robert A.
Pérez, Pedro J.
Albrecht, Martin
A series of novel 1,2,3-triazolylidene gold(i) chloride complexes have been synthesised and fully characterised. Silver-free methodologies for chloride ion abstraction of these complexes were evaluated for their potential as Au-based catalyst precursors. Using simple potassium salts or MeOTf as chloride scavengers produced metal complexes that catalyse both the regioselective synthesis of oxazolines and the C-H activation of benzene or styrene for carbene transfer from ethyl diazoacetate. These results indicate that Ag-free activation of 1,2,3-triazolylidene gold(i) chloride complexes is feasible for the generation of catalytically active Au triazolylidene species. However, silver-mediated activation imparts substantially higher catalytic activity in oxazoline synthesis.
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