Journal of Molecular Structure p. 249 - 268 (1994)
Update date:2022-08-17
Topics:
Sluyts, E. J.
Veken, B. J. Van der
Solutions containing several nitrogen oxide species have been investigated in liquefied argon in the temperature range 84-105 K, and in liquefied krypton in the temperature range 116-150 K, using infrared spectroscopy.The following nitrogen oxide species were characterised in these solutions: NO, cis-ONNO, trans-ONNO, the asymmetric dimer ONON, asymmetric ONNO2, symmetric ONONO and N2O4 with D2h symmetry.The enthalpy of dimerisation of NO to cis-ONNO has been determined in liquefied argon to be -14.3 +/- 1 kJ mol-1.
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