METAL EXCHANGE BETWEEN CADMIUM COMPLEXES
917
(Mechanisms of Organometallic Reactions), Moscow:
Khimiya, 1972.
–
lgkeff
2
3
2
1
2.7
2.6
2.5
2.4
2.3
2.2
2.1
6. Kukushkin, Yu.N. and Kukushkin, V.Yu., Teoriya i
praktika sinteza koordinatsionnykh soedinenii (The
Theory and Practice of the Synthesis of Coordination
Compounds), Leningrad: Nauka, 1990.
7. Entelis, S.G. and Tiger, R.P., Kinetika reaktsii v zhidkoi
faze (Reaction Kinetics in the Liquid Phase), Moscow:
Khimiya, 1973.
8. Berezin, B.D. and Enikolopyan, N.S., Metalloporphyꢀ
riny (Metalloporphyrins), Moscow: Nauka, 1988.
9. Karyakin, Yu.V. and Angelov, I.I., Chistye Khimicheskie
Veshchestva (Pure Chemicals), Moscow: Khimiya,
1974.
1.40
1.45
1.50
1.55
1.60
1.65
log
1.70
c
CoCl
2
10. Entelis, S.G. and Tiger, R.P., Kinetika reaktsii v zhidkoi
faze (Reaction Kinetics in the Liquid Phase), Moscow:
Khimiya, 1973.
–
0
Fig. 5. Plots of
reaction of CdChl(a) with СоСl in ethanol at Т = (1) 298,
(2) 308, and (3) 318 K.
vs.
in the metal exchange
lg kэфф
lg cCoCl
11. Berezin, V.D., Koordinatsionnye soedineniya porfirinov i
ftalotsianina (Coordination Compounds of Porphyrins
and Phthalocyanine), Moscow: Nauka, 1978.
2
2
2
12. Berezin, B.D. and Golubchikov, O.A., Koordinatsionꢀ
naya khimiya solvatokompleksov solei perekhodnykh
metallov (Coordination Chemistry of the Solvate Comꢀ
plexes of Transition Metal Salts), Moscow: Nauka,
1992.
CdPhe(a) less stable than CdChl(a) and thus more
tending toward metal exchange with СоСl2 in ethanol.
13. Berezin, B.D. and Enikolopyan, N.S., Porfiriny. Strukꢀ
tura. Svoistva. Sintez (Porphyrins. Structure. Properꢀ
ties. Synthesis), Moscow: Nauka, 1985, p. 49.
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anizmy reaktsii metalloorganicheskikh soedinenii
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY Vol. 36
No. 12
2010