Synthetic Communications p. 3693 - 3702 (2006)
Update date:2022-08-11
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Sisak, Attila
2-Aza-1,3-butadienes have been synthesized from carbonyl compounds and 1,1,1,3,3,3-hexamethyl-disilazane in the presence of cobalt-containing catalysts. The best yields (up to 95%) were achieved in the case of aldehydes branched in the α-position and 2-methylcyclohexanone. In the case of two α,β-unsaturated ketones, pyridine derivatives were found as the main products. Copyright Taylor & Francis Group, LLC.
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