ChemCatChem p. 389 - 392 (2017)
Update date:2022-08-30
Topics:
Perato, Serge
Large, Benjamin
Lu, Qiao
Gaucher, Anne
Prim, Damien
A highly efficient pyridylmethylamine-Pd alternative catalytic system for the C?H arylation of indole was explored. Variously substituted aryl groups were regio- and chemoselectively installed at the indole nucleus by using barium hydroxide as the base. The method was found to be efficient even in the presence of hindered coupling partners and Pd-reactive bonds.
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