Organic Letters
Letter
depended on the electronic properties of the substituents at the
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′ position. By decreasing the electron-donating capabilities of
the substituents (Me > F > NO ), the yield of the corresponding
2
amides (3k, 3i, and 3j) decreased from 98 to 82 to 49%,
respectively. Phthalimide and phthalic anhydride afforded
benzamide and benzoic acid in 17 and 51% yield, respectively,
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In summary, a general, chemoselective Ru-catalyzed reaction
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2
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appealing in many scenarios relevant to chemistry and biology,
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(
ASSOCIATED CONTENT
Supporting Information
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CCDC 1577926 contains the supplementary crystallographic
Crystallographic Data Centre, 12 Union Road, Cambridge
CB2 1EZ, UK; fax: +44 1223 336033.
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AUTHOR INFORMATION
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(c) Zhang, J.; Shrestha, R.; Hartwig, J. F.; Zhao, P. Nat. Chem. 2016, 8,
1
144. (d) Huang, L.; Biafora, A.; Zhang, G.; Bragoni, V.; Goossen, L. J.
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ORCID
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20) (a) Demerseman, B.; Mbaye, M. D.; Semeril, S.; Toupet, L.;
Notes
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(
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The authors declare no competing financial interest.
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(
891.
21) Coalter, J. N., III; Bollinger, J. C.; Huffman, J. C.; Werner-
ACKNOWLEDGMENTS
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Zwanziger, U.; Caulton, K. G.; Davidson, E. R.; Gerard, H.; Clot, E.;
Eisenstein, O. New J. Chem. 2000, 24, 9.
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Chem. - Eur. J. 2012, 18, 12873. (b) Manikandan, R.; Madasamy, P.;
Jeganmohan, M. ACS Catal. 2016, 6, 230.
This work was financially supported by CNRS, Universite
Rennes 1, China Scholarship Council (Ph.D. grant to Y.-C.Y.),
and Fondation Rennes 1 (Master grant to R.K.).
́
de
(23) Pattabiraman, V. R.; Bode, J. W. Nature 2011, 480, 471.
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