Guohua Liu et al.
COMMUNICATIONS
gen wascarefully releaesd. Dry CH 2Cl2 (1 mL) wasadded
and the mixture wasstirred for 1 min. The reactor then was
centrifuged (2000 r/min) for 1–2 min. The solution was puri-
fied by column chromatography using ether as the eluent.
The main peakswere concentrated to afford a mixture of
ketone and the corresponding alcohol as a colorless liquid
for determination of conversion and enantiomeric excess.
The conversion and enantiomeric excess were determined
via GC analysis using a Supelco b-Dex 120 chiral column
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(30 m0.25 mm(i.d.), 0.25 mm film) (see Supporting Infor-
A
mation for details).
Supporting Information
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Complete experimental proceduresand full characterization
data are given in the Supporting Information.
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Acknowledgements
We are grateful to China National Natural Science Founda-
tion (20673072), 973 Pre-program (2005CCA01100), Shang-
hai Sciences and Technologies Development Fund
(071005119 and 06JC14060), and Shanghai Municipal Edu-
cation Commission (No. 08YZ71) for financial support.
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Adv. Synth. Catal. 2008, 350, 1464 – 1468