Running title
Chin. J. Chem.
source Eco-utilization (Tianjin University of Science and Technolo-
gy), People’s Republic of China (BCERE202001).
[17] Chen, X.; Qian, P.; Zhang, T.; Xu, Z.; Fang, C.; Xu, X.; Chen, W.; Wu, P.; Shen,
Y.; Li, S.; Wu, J.; Zheng, B.; Zhang, W.; Huo, F. Catalyst Surfaces with Tunable
Hydrophilicity and Hydrophobicity: Metal-organic Frameworks toward Con-
trollable Catalytic Selectivity. Chem. Commun. 2018, 54, 3936-3939.
References
[
18] Sobhani, S.; Hosseini Moghadam, H.; Skibsted, J.; Sansano, J. M. A Hydro-
philic Heterogeneous Cobalt Catalyst for Fluoride-free Hiyama, Suzuki, Heck
and Hirao Cross-coupling Reactions in Pure Water. Green Chem. 2020, 22,
[
1] Walsh, C. T.; Moore, B. S. Enzymatic Cascade Reactions in Biosynthesis.
Angew. Chem. Int. Ed. 2019, 58, 6846−6879.
1
353-1365.
[
[
[
2] Sheldon, R. A.; Woodley, J. M. Role of Biocatalysis in Sustainable Chemistry.
Chem. Rev. 2018, 118, 801−838.
[
19] Bellini, R.; Chikkali, S. H.; Berthon-Gelloz, G.; Reek, J. N. H. Supramolecular
Control of Ligand Coordination and Implications in Hydroformylation Reac-
tions. Angew. Chem., Int. Ed. 2011, 50, 7342-7345.
3] Clomburg, J. M.; Crumbley, A. M.; Gonzalez, R. Industrial Biomanufacturing:
The Future of Chemical Production. Science, 2017, 355, aag0804.
[
20] Jouffroy, M.; Gramage-Doria, R.; Armspach, D.; Sémeril, D.; Oberhauser, W.;
Matt, D.; Toupet, L.; Confining Phosphanes Derived from Cyclodextrins for
Efficient Regio- and Enantioselective Hydroformylation. Angew. Chem., Int.
Ed. 2014, 53, 3937-3940.
4] France, S. P.; Hepworth, L. J.; Turner, N. J.; Flitsch, S. L. Constructing Biocat-
alytic Cascades: In Vitro and in Vivo Approaches to de Novo Multi-Enzyme
Pathways. ACS Catal. 2017, 7, 710-724.
[
5] He, Z.; Dong, B.; Wang, W.; Yang, G.; Cao, Y.; Wang, H. J.; Yang, Y.; Wang, Q.;
Peng, F.; Yu, H. Elucidating Interaction between Palladium and N-doped
Carbon Nanotubes: Effect of Electronic Property on Activity for Nitroben-
zene Hydrogenation. ACS Catal. 2019, 9, 2893-2901.
[
21] Jeon, W. S.; Moon, K.; Park, S. H.; Chun, H.; Ko, Y. H.; Lee, J. Y.; Lee, E. S.;
Samal, S.; Selvapalam, N.; Rekharsky, M. V.; Sindelar, V.; Sobransingh, D.;
Inoue, Y.; Kaifer, A. E.; Kim, K.; Complexation of Ferrocene Derivatives by
the Cucurbit[7]uril Host:ꢀ A Comparative Study of the Cucurbituril and Cy-
clodextrin Host Families. J. Am. Chem. Soc. 2005, 127, 12984-12989.
[6] Liu, L.; Corma, A. Metal Catalysts for Heterogeneous Catalysis: From Single
Atoms to Nanoclusters and Nanoparticles. Chem. Rev. 2018, 118,
[
[
[
4981-5079.
[
7] Li, X.; Zhang, B.; Tang, L.; Goh, T. W.; Qi, S.; Volkov, A.; Pei, Y.; Qi, Z.; Tsung,
C.; Stanley, L. Cooperative Multifunctional Catalysts for Nitrone Synthesis:
Platinum Nanoclusters in Amine-Functionalized Metal–Organic Frame-
works. Angew. Chem. 2017, 129, 16589-16593.
Chem. Soc. 2014, 136, 12092-12098.
[
8] Görbe, T.; Gustafson, K. P. J.; Verho, O.; Kervefors, G.; Zheng, H.; Zou, X.;
Johnston, E. V.; Bäckvall, J.-E. Design of a Pd(0)-CalB CLEA Biohybrid Catalyst
and Its Application in a One-Pot Cascade Reaction. ACS Catal. 2017, 7,
24] Osako, T.; Srisa, J.; Torii, K.; Hamasaka, G.; Uozumi, Y. Iterative Preparation
of Platinum Nanoparticles in an Amphiphilic Polymer Matrix: Regulation of
Catalytic Activity in Hydrogenation. Synlett 2020, 31, 147-152.
1601-1605.
25] Osako, T.; Kaiser, R.; Torii, K.; Uozumi, Y. Aqueous Flow Hydroxycarbonyla-
tion of Aryl Halides Catalyzed by an Amphiphilic Polymer-Supported Palla-
dium-Diphenylphosphine Catalyst Synlett 2019, 30, 961-966.
[
9] Rudroff, F.; Mihovilovic, M. D.; Gröger, H.; Snajdrova, R.; Iding, H.;
Bornscheuer, U. T. Opportunities and Challenges for Combining Chemo- and
Biocatalysis. Nat. Catal. 2018, 1, 12-22.
26] Shen, G.; Osako, T.; Nagaosa, M.; Uozumi, Y. Aqueous Asymmetric
[
[
[
10] White, R. J.; Luque, R.; Budarin, V. L.; Clark, J. H.; Macquarrie, D. J. Support-
ed Metal Nanoparticles on Porous Materials. Methods and Applications.
Chem. Soc. Rev., 2009, 38, 481.
1,4-Addition of Arylboronic Acids to Enones Catalyzed by an Amphiphilic
Resin-Supported Chiral Diene Rhodium Complex under Batch and Continu-
ous-Flow Conditions. J. Org. Chem. 2018, 83, 7380−7387.
11] Rodrigues, R. C.; Ortiz, C.; Berenguer-Murcia, Á.; Torres, R.; Fernán-
dez-Lafuente, R. Modifying Enzyme Activity and Selectivity by Immobiliza-
tion. Chem. Soc. Rev. 2013, 42, 6290-6307.
[
[
[
[
[
27] Pan, S.; Yan, S.; Osako, T.; Uozumi, Y. Batch and Continuous-Flow Huisgen
1,3-Dipolar Cycloadditions with an Amphiphilic Resin-Supported Tria-
zine-Based Polyethyleneamine Dendrimer Copper Catalyst. ACS
Sustain-
able Chem. Eng. 2017, 5, 10722−10734.
12] Zhou, Z.; Hartmann, M. Progress in Enzyme Immobilization in Ordered
Mesoporous Materials and Related Applications. Chem. Soc. Rev., 2013, 42,
28] Hao, Y.; Jiao, X.; Zou, H.; Yang, H.; Liu, J. Growing a Hydrophilic Nanoporous
Shell on a Hydrophobic Catalyst Interface for Aqueous Reactions with High
Reaction Efficiency and in Situ Catalyst Recycling. J. Mater. Chem. A. 2017,
3894-3912.
[13] Hwang, E. T.; Lee, S. Multienzymatic Cascade Reactions via Enzyme Complex
5, 16162-16170.
by Immobilization. ACS Catal. 2019, 9, 4402-4425.
29] Shan, B.-Q.; Xing, J.-L.; Yang, T.-Q.; Peng, B.; Hao, P.; Zong, Y.-X.; Chen, X.-Q.;
Xue, Q.-S.; Zhang, K.; Wu, P. One-pot Co-condensation Strategy for Dendrit-
ic Mesoporous Organosilica Nanospheres with Fine Size and Morphology
Control. CrystEngComm. 2019, 21, 4030-4035.
[
14] Cortes-Clerget, M.; Yu, J.; Kincaid, J. R. A.; Walde, P.; Gallou, F.; Lipshutz, B.
H. Water as The Reaction Medium in Organic Chemistry: From Our Worst
Enemy to Our Best Friend. Chem. Sci. 2021, DOI: 10.1039/d0sc06000c.
[
15] Lipshutz, B. H.; Ghorai, S.; Cortes-Clerget, M. The Hydrophobic Effect Ap-
plied to Organic Synthesis: Recent Synthetic Chemistry “in Water”. Chem.
Eur. J. 2018, 24, 6672-6695.
30] Yang, Y.; Bernardi, S.; Song, H.; Zhang, J.; Yu, M.; Reid, J. C.; Strounina, E.;
Searles, D. J.; Yu, C. Anion Assisted Synthesis of Large Pore Hollow Dendritic
Mesoporous Organosilica Nanoparticles: Understanding the Composition
Gradient. Chem. Mater, 2016, 28, 704-707.
[
16] Gallou, F.; Isley, N. A.; Ganic, A.; Onken, U.; Parmentier, M. Surfactant
Technology Applied toward an Active Pharmaceutical Ingredient: More than
a Simple Green Chemistry Advance. Green Chem. 2016, 18, 14-19.
31] Gao, L.; Wang, Z.; Liu, Y.; Liu, P.; Gao, S.; Gao, J.; Jiang, Y. Co-immobilization
of Metal and Enzyme into Hydrophobic Nanopores for Highly Improved
Chin. J. Chem. 2021, 39, XXX-XXX
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