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diazocarbonyl anions with conjugate olefins/benzyne comple-
ments the previous methods on carrying phosphonate in the
end products. The isolation of 2-diazo-1-phenylethan-1-one
and the tracing of the presence of intermediate dimethyl
phosphorofluoridate by HRMS support our proposal of the
fluoride-mediated dephosphonylation.
ASSOCIATED CONTENT
* Supporting Information
■
S
The Supporting Information is available free of charge on the
Experimental procedure, characterization of new com-
pounds (1H, 13C NMR, HRMS spectra), and X-ray
crystallographic data (PDF)
AUTHOR INFORMATION
■
Corresponding Author
ORCID
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
We thank the CSIR for funding this project under the 12 FYP
ORIGIN Program (CSC0108) and a research fellowship to
RSP.
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