Tetrahedron Letters p. 2017 - 2020 (2016)
Update date:2022-08-16
Topics:
Chang, Sheng
Jin, Ying
Zhang, Xiu Rong
Sun, Yong Bing
An efficient protocol has been developed for the carbonylative Hiyama coupling of aryl halides using the cesium fluoride as a promoter by palladium-catalyzed in NMP. This protocol was applied to a wide variety of functionalized and hindered aryl iodides and bromides with arylsilanes, to afford the desired biaryl ketones in good to excellent yields.
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