Organometallics p. 2480 - 2485 (1994)
Update date:2022-08-17
Topics:
Cunningham Jr., Allan F.
(Pentadeuteriocyclopentadienyl)cyclopentadienyliron(II), 4, was prepared by the sequential addition of lithium tris(trimethylsilyl)cyclopentadienide and lithium pentadeuteriocyclopentadienide to FeBr2 followed by fluoride-induced removal of the trimethylsilyl groups of the resulting ferrocene 3. Analysis of the deuterium content of the acetylferrocene 5 and the 1,1′-diacetylferrocene 7, obtained from the Friedel-Crafts acetylation of 4, reveals that the former is formed by initial exo attack of AlCl3-CH3COCl, whereas precomplexation of the electrophile at the metal center (endo attack) precedes the formation of the latter.
View MoreNingbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Contact:+86-0760-85282375
Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Luzhou North Chemical Co., Ltd.
Contact:+86-830-2796784;+86-830-2796776
Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
website:http://www.sagechem.com
Contact:+86-571-86818502
Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Taizhou Shengxing Chempharm Co.,Ltd
Contact:+86-576-88516600
Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Doi:10.1021/jo01161a022
(1948)Doi:10.1021/om00136a009
(1986)Doi:10.1111/cbdd.12491
(2015)Doi:10.1016/0031-9422(82)83025-2
(1982)Doi:10.1248/cpb.37.697
(1989)Doi:10.1039/c3cc49439j
(2014)