364 Ilia et al.
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8
[
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To a mixture of 0.01 mol K PO4,0.015 mol alcohol,
3
[
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8219.
and 0.0005 mol tetrahexylammonium chloride as
catalyst in 10 mL methylene chloride, under stir-
ring and external cooling (ice bath) 0.01 mol di-
ethylchlorophosphite in 5 mL methylene chloride
was added dropwise. The temperature was kept un-
[
◦
der 10 C during the addition of diethylchlorophos-
[
[
17] Marelli, C.; Monti, C.; Gennari, C.; Piarulli, U. Synlett
◦
phite, then the mixture was kept another 3 h at 20 C.
The mixture was filtered; the solvent was removed
by distillation, and the product was purified by dis-
2
007, 2213–2216.
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◦
(
C
3
H
7
O)P(OC
2
H
5
)
2
, liquid, bp 74 C/23 mmHg,
[
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83–691.
3
1
1
P{ H}, δ
P
:138.5 ppm. (i-C
3
H
7
O)P(O C
: 139 ppm (lit. [36]:
2
H
5
2
) , liquid,
6
◦
31
1
bp 76 C/20 mmHg, P{ H}, δ
P
[
21] Harizi, A.; Zaitor, H. Phosphorus, Sulfur 2004,
179(9), 1883–1891.
◦
1
37.3 ppm). (n-C
4
H
9
O)P(O C
2
H
5
)
2
, liquid, bp 72 C/10
O) P(OC Cl),
: 137 ppm.
3
1
1
mmHg, P{ H}, δ
P
: 139 ppm. (C
2
H
5
2
2
H
4
[22] Piekutowska, M.; Pakulski, Z. Tetrahedron Lett 2007,
48, 8482–8486.
◦
31
1
liquid, bp 115 C/5 mmHg, P{ H}, δ
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[
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Heteroatom Chemistry DOI 10.1002/hc