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Indeed, the presence of methyl 2-aminocinnamate was detected only in
the case of reactions conducted in the presence of Ru
3
(CO)12 (alone or
in combination with [Pd(Phen) ][BF ). The ability of Ru to catalyze the
2
4 2
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11] Reaction conditions for the n-butyl formate protocol are those reported in
Table S1: 0.27 mmol nitro compound, 1 mol % [Pd(Phen)
mol % Ru (CO)12, 20 mol % Phen, 2 equiv. Et N, 10 mL HCOOnBu,
80 °C, 10 h. Reaction vessel was a ACE Pressure Tube.
2 4 2
][BF ] , 1
3
3
1
[
[
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