Angewandte Chemie International Edition
10.1002/anie.201802466
fluorination process (including its detailed reaction mechanism) is
currently underway in our laboratory.
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Received: ((will be filled in by the editorial staff))
Published online on ((will be filled in by the editorial staff))
Keywords: diazonium • fluorination • Balz-Schiemann • aryliodonium
[
[
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[14] There is only subtle difference in the chemical shifts between p-TolIF
2
and the corresponding aryliodonium (III), and the latter alone seems
unstable in non-coordinated solvent. The signals are compared in
1
[
[
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CD
See SI for more details.
and I are sensitive to moisture and glass, while I
For their synthesis, see SI for details.
A
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3
CN to confirm the form of the hypervalent iodine(III) compound.
[15]
I
A
B
C
is quite stable.
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C
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2
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-
[
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employed compound 4 for this study (PF
6
counterion was used to
improve the reactivity; see: ref 9b) .
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4
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