DOI: 10.1039/C5GC00580A
Green Chemistry
%
increase of selectivity were achieved for both fructose and 65 11 C. Moreau, A. Finiels, L. Vanoye, J. Mol. Catal. A: Chem., 2006,
2
53, 165.
(a) H. B. Zhao, J. E. Holladay, H. Brown, and Z. C. Zhang, Science,
007, 316, 1597-1600; (b) G. Yong, Y. G. Zhang, J. Y. Ying,
glucose dehydrations in emulsion system as compared to the
conventional biphasic system. The excellent recyclability of the
nanoparticles also further widens the potential of the biphasic
system to be scaled up for industrial application.
1
2
2
Angew. Chem., Int. Ed. 2008, 47, 9345; (c) L. Lai, Y. G. Zhang,
ChemSusChem 2010, 3, 1257; (d) M. X. Tan, L. Zhao, Y. G. Zhang,
Biomass and Bioenergy, 2011, 35, 1367.
(a) S. Lima, P. Neves, M. M. Antunes, M. Pillinger, N. Ignatyev, A.
A. Valente, Appl. Catal., A 2009, 363, 93; (b) Y. Roman-Leshkov,
C. J. Barrett, Z. Y. Liu an J. A. Dumesic, Nature 2007, 447, 982; (c)
M. Chidambaram, A. Bell, Green Chem. 2010, 12, 1253; (d) Q. X.
Bao, K. Qiao,D. Tomida, C. Yokoyama, Catal. Commun. 2008, 9,
5
70
75
80
1
3
Acknowledgements
This work was supported by the Institute of Bioengineering and
Nanotechnology (Biomedical Research Council, Agency for
Science, Technology and Research (A*STAR), Singapore),
Biomass-to-Chemicals Program (Science and Engineering
Research Council, A*STAR, Singapore).
1
1
383; (e) J. B. Binder, R. T. Raines, J. Am. Chem. Soc. 2009, 131,
1
0
Shanks, Green Chem., 2014, 16, 548.
(a) S. Q. Hu, Z. F. Zhang, J. L. Song, Y. X. Zhou, B. X. Han, Green
Chem. 2009, 11, 1746; (b) J. Y. G. Chan, Y. G. Zhang,
ChemSusChem 2009, 2, 731.
(a) S. Crossley, J. Faria, M. Shen, D. E. Resasco, Science, 2010, 327,
68; (b) L. Leclercq, A. Mouret, A. Proust, V. Schmitt, P. Bauduin,
J.-M. Aubry, V. Nardello-Rataj, Chem. Eur. J., 2012, 18, 14352; (c)
H. Yang, T. Zhou, W. Zhang, Angew. Chem. Int. Ed., 2013, 52,
1
1
4
5
Notes and references
Institute
1 Biopolis Way, The Nanos, Singapore 138669.
E-mail: ygzhang@ibn.a-star.edu.sg
Electronic Supplementary Information (ESI) available: details of
experiments and computational study. See DOI: 10.1039/b000000x/
of
Bioengineering
and
Nanotechnology
8
9
9
5
0
5
3
1
2
2
3
3
4
4
5
5
6
5
0
5
0
5
0
5
0
5
0
†
7
455; (d) S. Wiese, A. C. Spiess, W. Ritchtering, Angew. Chem. Int.
Ed., 2013, 52, 576; (e) W.-J. Zhou, L. Fang, Z. Fan, B. Albela, L.
Bonneviot, F. D. Campo, M. Pera-Titus, J.-M. Clacens, J. Am.
Chem. Soc., 2014, 136, 4869; (f) H. Liu, Z. Zhang, H. Yang, F.
Cheng, Z. Du, ChemSusChem, 2014, 7, 1888; (g) Z. Chen, L. Zhou,
W. Bing, Z. Zhang, Z. Li, J. Ren, X. Qu, J. Am. Chem. Soc., 2014,
1
(a) A. Corma, S. Iborra and A. Velty, Chem. Rev. 2007, 107, 2411;
(b) P. Gallezot, Green Chem. 2007, 9, 295; (c) C. H. Christensen, J.
Rass-Hansen, C. C. Marsden, E. Taarning, K. Egeblad, The
renewable chemicals industry, 2008, 1, 283.
(a) B. Kamm, Angew. Chem. Int. Ed. 2007, 46, 5056; (b) Lichten-
thaler F. W. Biorefinerier – Industrial Processes and Products,
Wiley-VCH, Weinheim, 2006.
(d) D. Tilman, R. Socolow, J. A. Foley, J. Hill, E. Larson, L. Lynd,
S. Pacala, J. Rrilly, T. Searchinger, C. Somerville, R. Williams,
Science, 2009, 325, 270.
1
36, 7498; (h) Y. Yang, Z. Du, J. Ma, F. Lu, J. Zhang, J. Xu,
2
3
ChemSusChem, 2014, 7, 1352; (i) M. Pera-Titus, L. Leclercq, J.-M.
Clacens, F. De Campo, V. Nardello-Rataj, Angew. Chem. Int. Ed.,
DOI: 10.1002/anie.201402069.
1
1
6
7
L. Wang, F.-S. Xiao, ChemCatChem, 2014, 6, 3048.
L. Wang, H. Wang, F. Liu, A. Zheng, J. Zhang, Q. Sun, J. P. Lewis,
L. Zhu, X. Meng, F.-S. Xiao, ChemSusChem, 2014, 7, 402-406.
(a) S. P. Teong, X. Cao, G. Yi, Y. Zhang, ChemSusChem, 2014, 7,
1
1
00
4
5
J. P. Holdren, Science 2007, 315, 737.
G. W. Huber, J. N. Chheda, C. J. Barrett, J. A. Dumesic, Science,
1
8
2
120; (b) X. Cao, S. P. Teong, D. Wu, G. Yi, H. B. Su, Y. Zhang,
2
005, 308, 1446.
Green Chem., 2014, 17, 2348.
W. Stöber, A. Fink, E. Bohn, J. Colloid Interface Sci., 1968, 26, 62.
6
Selected reviews for HMF production and HMF chemistry: (a) B. F.
M. Kuster, Starch/Staerke, 1990, 42, 314; (b) L. Cottier, G.
Descotes, Trends Heterocycl. Chem., 1991, 2, 233; (c) J.
Lewkowski, Arkivoc, 2001, 2, 17; (d) C. Moreau, M. N. Belgacem,
A. Gandini, Top. Catal., 2004, 27, 11; (e) A. Boisen, T. B.
Christensen, W. Fu, Y. Y. Gorbanev, T. S. Hansen, J. S. Jensen, S.
K. Klitgaard, S. Pedersen, A. Riisager, T. Stahlberg, J. M. Woodley,
Chem. Eng. Res. Des., 2009, 87, 1318; (f) J. C. Serrano-Ruiz, R. M.
West, J. A. Dumesic, Annu. Rev. Chem. Biomol. Eng. 2010, 1, 79;
1
9
05 20 W. Zhang, L. Fu, H. Yang, ChemSusChem, 2013, 7, 391.
2
1
M. A. Mellmer, C. Sener, J. M. R. Gallo, J. S. Luterbacher, D. M.
Alonso, J. A. Dumesic, Angew. Chem. Int. Ed, 2014, 53, 11872.
(
g) M. J. Climent, A. Corma, S. Iborra, Green Chem. 2011, 13, 520;
(h) A. A. Rosatella, S. P. Simeonov, R. F. M. Frade, C. A. M.
Afonso, Green Chem. 2011, 13, 754; (i) X. L. Tong, Y. Ma, Y.D.
Li, Appl. Catal., A, 2010, 385, 1; (j) S. Dutta, RSC Adv. 2012, 2,
12575; (k) A. M. Ruppert, K. Weinberg, R. Palkovits, Angew.
Chem. Int. Ed., 2012, 51, 2564; (l) Y. G. Zhang, J. Y. G. Chan,
Energy Environ. Sci. 2010, 3, 408; (m) S. P. Teong, G. Yi, Y.
Zhang, Green Chem. 2014, 16, 2015; (n) van Putten R. J.; van der
Waal J. C.; de Jong E.; Rasrendra C. B.; Heeres H. J.; de Vries J. G.
Chem. Rev. 2013, 113, 1499; (o) Wang T.; Nolte M. W.; Shanks
B. H.; Green Chem. 2014, 16, 548.
C. O. Tuck, E. Perez, I. T. Horvath, R. A. Sheldon, M. Poliakoff,
Science, 2012, 337, 695.
(a) T. Werpy, G. Petersen, Top Value Added Chemicals from
Biomass, NREL/TP-510-35523, National Renewable Energy La-
boratory, Golden, CO, 2004; (b) J. J. Bozell, Science, 2010, 329,
7
8
5
7
1
22; (c) G. Yi, S. P. Teong, X. Li, Y. Zhang, ChemSusChem, 2014,
, 2130; (d) G. Yi, S. P. Teong, Y. Zhang, ChemSusChem, 2015, 8,
151; (e) X. Li, D. Wu, G. Yi, H. Su, Y. Zhang, Angew. Chem. Int.
Ed. 2014, 53, 4200.
9
1
D. W. Brown, A. J. Floyd, R. G. Kinsman, Y. Roshanali, J. Chem.
Techn. Biotechn., 1982, 32, 920.
J. N. Chheda, Y. Roman-Leshkov, and J. A. Dumesic, Green Chem.,
0
2
007, 9, 342.
4
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